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Multidimensional database This is an additional database that enables end users to quickly retrieve and present complex data that involve many dimensions (see 11) Deductive databases Hierarchical, network, and relational DBMSs have been used for decades to facilitate data access by users Users, of course, must understand what they are looking for, the database they are looking at, and at least something about the information sought (like a key and some eld or attribute about a record) This approach, however, may not be adequate for some knowledge-based applications that require deductive reasoning for searches As a result, there is interest in what is called deductive database systems Multimedia and hypermedia databases These are analogous to contemporary databases for textual and numeric data; however, they have been tailored to meet the special requirements of dealing with different types of media materials (see 11) Small-footprint databases.

COACHING INTO GREATNESS of circumstances and mitigating factors, that person is doing their best based on what they know and feel at that time Self-Empathy is extending this notion of doing the best you can inward When we re comparing ourselves to others, the tendency is to beat ourselves up We are our own worst enemies And so our internal boxing match ends up being projected on the people and situations in our external world It s not often a pretty sight Self-Empathy is the ability to internalize loving kindness, and at the same time relate to others more powerfully and authentically because we re no longer defending ourselves The key to Self-Empathy is an internal inquiry process in which we learn to see the truth in spite of any existing conditions or circumstances Author Joyce Meyer says that you are the one person you can never get away from Yet, so many lives are spent searching furiously for the things that will help us do just that, as if we can ever leave ourselves behind To break this cycle, we must practice Self-Empathy: Acceptance of who you are and who you ll never be (both are true) Separate the intended outcome from the actual outcome Practice the Tibetan philosophy of loving kindness compassion for ourselves and all living things Celebrate what is, not what was or what could be For example, say that your client is experiencing a huge downturn in his business In fact, his bank account is rapidly approaching zero He s scared and desperate for some answers His view of the world at

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Figure 31 Four-step construction of the Bjerrum difference plot for a three-pKa molecule, whose constants are obscured in the simple titration curve (see text): (a) titration curves; (b) isohydric volume differences; (c) rotated difference plot; (d) Bjerrum plot [Avdeef, A, Curr Topics Med Chem, 1, 277 351 (2001) Reproduced with permission from Bentham Science Publishers, Ltd]

Small-footprint databases enable organizations to put certain types of data in the eld where the workers areWhereas laptops were once the only portable machines capable of running a database, advances in technology (eg, more powerful CPUs and increased memory at lower cost) are enabling handheld devices and smart phones to run some form of an SQL database and to synchronize that mobile database with a central database at headquarters The name comes from the fact that the engines running these databases (eg, Access) typically are small, and thus the databases do not use a lot of space in memory Small-footprint databases have replication mechanisms that take into account the occasionally connected nature of laptops and handhelds, that are programmed to resolve replication con icts among mobile users, and that ensure that data synchronization will survive a low-quality wireless or modem connection.

concentration divided by that of the sample gives the average number of bound hydrogen atoms per molecule of substance "H The Bjerrum curve is a plot of "H n n versus pcH Operationally, such a plot can be obtained by subtracting a titration curve containing no sample ( blank titration; left curve in Fig 31a) from a titration curve with sample (right curve in Fig 31a) at xed values of pH The resultant difference plot is shown in Fig 31b The plot is then rotated (Fig 31d), to emphasize that "H n is the dependent variable and pH is the independent variable [163] The volume differences can be converted to proton counts as described in the preceding paragraph, to obtain the nal form, shown in Fig 31d The Bjerrum plot in Fig 31d reveals all the pKa terms as pcH values at halfintegral "H positions The three pKa values of M6G are evident: 28, 82, and n 94 In contrast to this, deducing the constants by simple inspection of the titration curves is not possible (Fig 31a): (1) the low pKa is obscured in Fig 31a by the buffering action of water and (2) the apparent pKa at pH 88 is misleading M6G has two overlapping pKa terms, whose average value is 88 M6G nicely illustrates the value of Bjerrum analysis With Bjerrum analysis, overlapping pKa s pose no dif culty Figure 32a shows an example of a 6-pKa molecule, vancomycin [162,166] Figure 32b shows an example of a 30-pKa molecule, metallothionein, a small heavy-metal-binding protein, rich in sulfhydryl groups [167] (The reader is challenged to identify the six ionization sites of vancomycin)

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